====== Chemistry ====== $$\require{mhchem}$$ [[Notes on Khan Academy Chemistry]] [[History of Chemistry]] [[Atom, Element, Periodic Table, Ion, Isotope]] [[Periodic Table of Elements]] [[Molecule, Bond, Formula, Nomenclature]] [[Chemical Reactions, Equations]] Types of chemical reactions: [[Acid, Base, Salt]] [[Heat, Cooking]] [[Radiation, Explosives]] [[Electrochemical Reactions]] ===== Terms ===== Atom Element Molecule - bonds Compound - bonds Mixture - no bonds ? Bonds Characteristics of Elements solid, liquid, gas Heavy Metals Precious Metals Nutritional Metals Poisons Silly Symbols Date Discovered, historicity, alchemy Named after people Named after planets Named after places Silly names: Unobtanium Radioactive Elements ===== Atoms ===== ==== Atomic Structure ==== Atomic Structure, shells, traits, bonds, reactions YouTube:AtomicSchool playlist https://www.youtube.com/playlist?list=PLYbDrmR0pxgrTmNsqqSXC-6xrJIkCjpfo ==== Characteristics of Elements ==== ===== Molecules ===== ==== Molecular Structure ==== ==== Characteristics of Compounds ==== acid = molecule or ion capable of: * donating a proton * making a covalent bond with an electron pair ===== Energy States ====== electrons electro-negativity how energy is released or required when an electron changes state shell = energy level outer shells have higher energy level ? ===== Electron Configuration ===== ==== Binding Energy ==== shells subshells and orbitals Electrons closer to the nucleus have a higher binding energy. They are bound more tightly to the nucleus. It takes more energy to knock them away from the nucleus. {{https://youtu.be/UaTWrOTh4qU | Salman Khan: Introduction to photoelectron spectroscopy}} Atoms are bombarded with XRay photons which knock the electrons away from the nucleus onto a detector. The detector then gives us a map of the binding energy of the electrons. The photoelectron spectrum. Electrons from the outer shell fly the farthest because they have the lowest binding energy. ==== Valence ==== {{https://youtu.be/cZTdBsAjPPk | Salman Khan: Valence electrons}} Knowing the configuration of electrons in an atom gives us clues as to how that atom will react to other atoms. * is it reactive or inert? * will it dissolve in water? hydrophobia, hydrophillic (attraction, repulsion) * is it electronegative * does it conduct electricity * does it have polarity * does it have a charge? neutral, positive, or negative * is it radioactive? * at what temperature does it convert from solid to liquid to gas? * ==== Atomic radius ==== {{https://youtu.be/q--2WP8wXtk | Salman Khan: Atomic radius trends on periodic table}} Coulomb attraction: between nucleus and electrons. Atoms get smaller trending to the right on the periodic table. Because the larger number of protons creates a stronger positive charge in the nucleus and the larger number of valence electrons creates a stronger negative charge in the outer shell. So these stronger charges pull the electron shells in closer to the nucleus. So krypton is smaller than potassium. It has more protons and electrons, so you might think it would be bigger. But it is smaller because of the increased charge. Helium is the smallest atom. Smaller than hydrogen. The radius increases down and to the right across the periodic table. Down, because each additional shell is farther away from the nucleus. To the right, because the charge between the nucleus and the outer shell increases. ===== Analytic Chemistry ===== Analyze a mixture. What chemicals are there by mass? isotopes atomic mass for each element Sal Khan working math problems. 1. NaCl plus contaminates. https://www.khanacademy.org/science/chemistry/x822131fc:more-about-mixtures/x822131fc:mixtures/v/worked-example-analyzing-purity-of-a-mixture?modal=1 sodium chloride NaCl sodium iodide NaI potassium chloride KCl lithium chloride LiCl Na Cl I K Li 2. Potassium supplement as KCl, g per mol, mass, mol, molar mass https://www.khanacademy.org/science/chemistry/x822131fc:more-about-mixtures/x822131fc:mixtures/v/worked-example-calculating-mass-of-substance-in-mixture?modal=1 Sal Khan: Isotopes and mass spectrometry https://www.khanacademy.org/science/chemistry/x822131fc:untitled-537/mass-spectrometry/v/mass-spectrometry?modal=1 how spectrometry is used to detect and measure the amounts of isotope in a sample using zirconium Zr as an example Sal Khan: Identifying an element from its mass spectrum https://www.khanacademy.org/science/chemistry/x822131fc:untitled-537/mass-spectrometry/v/worked-example-identifying-element-from-mass-spectrum?modal=1 using strontium Sr as an example ===== References ===== Wikipedia: "Chemistry", [[https://en.wikipedia.org/wiki/Chemistry]], Retrieved 23-Mar-2019. Khan Academy: "Chemistry", [[https://www.khanacademy.org/science/chemistry]], Retrieved 23-Mar-2019. [[Notes on Khan Academy Chemistry|Notes]] Primrose Kitten: "The whole of ATOMIC STRUCTURE in 20 minutes!", [[https://www.youtube.com/watch?v=sYlmoNKypoY]], Retrieved 23-Mar-2019. [[Notes on Primrose Kitten Chemistry|Notes]] Crash Course: "The History of Atomic Chemistry",[[https://www.youtube.com/watch?v=thnDxFdkzZs]], Retrieved 23-Mar-2019. [[Notes on Crash Course Chemistry|Notes]] NIH: PubChem (open chemistry database) [[https://pubchem.ncbi.nlm.nih.gov/]] Professor Dave Explains: "General Chemistry", https://youtube.com/playlist?list=PLybg94GvOJ9EbbO2RXPWTUNIIE0C7hSfm